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Synthesis and magnetic properties of new dinuclear iron(II) complexes of a phenylene-bridge shiff base analogue dinucleating ligand

Title data

Weber, Birgit ; Kaps, Eike:
Synthesis and magnetic properties of new dinuclear iron(II) complexes of a phenylene-bridge shiff base analogue dinucleating ligand.
In: Heteroatom Chemistry. Vol. 16 (2005) Issue 5 . - pp. 391-397.
ISSN 1042-7163
DOI: https://doi.org/10.1002/hc.20108

Abstract in another language

The synthesis and magnetic behavior of four new dinuclear iron(II) complexes Fe22a-d × 4Py with the iron in an octahedral coordination sphere is presented in this paper. The complex c is a high-spin complex over the whole temperature range investigated, while the complexes a,b, and d perform a partial low-spin ⇔ high-spin spin transition. In case of Fe22b × 4Py, X-ray structure analysis of the HS/LS state was possible, showing that in one molecule both iron centers are either in the low-spin or sin the high-spin state.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV > Chair Anorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 25 Jul 2017 09:46
Last Modified: 25 Jul 2017 09:46
URI: https://eref.uni-bayreuth.de/id/eprint/38865