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Attractive and Repulsive Electrostatic Forces between Positively Charged Latex Particles in the Presence of Anionic Linear Polyelectrolytes

Title data

Popa, Ionel ; Gillies, Graeme ; Papastavrou, Georg ; Borkovec, Michal:
Attractive and Repulsive Electrostatic Forces between Positively Charged Latex Particles in the Presence of Anionic Linear Polyelectrolytes.
In: The Journal of Physical Chemistry B. Vol. 114 (2010) Issue 9 . - pp. 3170-3177.
ISSN 1520-5207
DOI: https://doi.org/10.1021/jp911482a

Official URL: Volltext

Abstract in another language

The interaction forces between individual positively charged amidine functionalized latex particles with adsorbed negatively charged sodium poly(styrene sulfonate) were studied with the colloidal probe technique based on atomic force microscopy (AFM). When the polymer dose is progressively increased, the strength of the repulsive force between the particles decreases as the charge neutralization point is approached, then increases again due to overcharging, and finally reaches a plateau. Surface potentials obtained from fits of the force profiles to Poisson-Boltzmann theory agree well with potentials measured with electrophoresis. Close to the charge neutralization point, attractive forces exceeding van der Waals interactions are found. These attractive forces increase in strength with increasing molecular mass of the polymer and decreasing ionic strength. These attractive interactions are of electrostatic origin and result from lateral patch-charge heterogeneities within the adsorbed polyelectrolyte layer. The measured forces are shown to be in semiquantitative agreement with model calculations based oil charge distributions with square lattice symmetry.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Physical Chemistry II
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Former Professors > Chair Physical Chemistry II - Univ.-Prof. Dr. Andreas Fery
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Physical Chemistry II
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Former Professors
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 12 Sep 2017 10:49
Last Modified: 12 Sep 2017 10:49
URI: https://eref.uni-bayreuth.de/id/eprint/39564