Title data
Okolieocha, Chimezie ; Beckert, Fabian ; Herling, Markus M. ; Breu, Josef ; Mülhaupt, Rolf ; Altstädt, Volker:
Preparation of microcellular low-density PMMA nanocomposite foams : Influence of different fillers on the mechanical, rheological and cell morphological properties.
In: Composites Science and Technology.
Vol. 118
(August 2015)
.
- pp. 108-116.
ISSN 1879-1050
DOI: https://doi.org/10.1016/j.compscitech.2015.08.016
Abstract in another language
Poly(methyl methacrylate) (PMMA) nanocomposites were prepared by incorporating talc, carbon black (CB) and thermally reduced graphite oxide (TRGO) respectively. At a loading content of 5 wt %, the fillers were well dispersed within the PMMA matrix with the exception of CB. As expected, the inclusion of the respective fillers led to an increase of the tensile modulus at the expense of tensile strength and elon-gation at break compared to neat PMMA. The addition of TRGO (5 wt %) increased the dynamic complex shear viscosity (h*) and storage modulus (G /) of PMMA by one order of magnitude compared to talc and CB at the same concentration. Van Gurp-Palmen-plot further revealed the formation of filler network only for CB and TRGO particles. Physisorption measurements showed that TRGO and CB fillers were more CO 2-phillic in comparison to talc and may have contributed to increasing the amount of CO 2 retention as confirmed by sorption measurements. These features were exploited to prepare closed-cell microcellular low-density PMMA nanocomposite foams via batch-foam process.
Further data
Item Type: | Article in a journal |
---|---|
Refereed: | Yes |
Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry I > Chair Inorganic Chemistry I - Univ.-Prof. Dr. Josef Breu Faculties > Faculty of Engineering Science > Chair Polymer Materials > Chair Polymer Materials - Univ.-Prof. Dr.-Ing. Volker Altstädt Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry I Faculties > Faculty of Engineering Science Faculties > Faculty of Engineering Science > Chair Polymer Materials |
Result of work at the UBT: | Yes |
DDC Subjects: | 500 Science > 540 Chemistry |
Date Deposited: | 29 Mar 2018 07:28 |
Last Modified: | 15 Jul 2020 13:01 |
URI: | https://eref.uni-bayreuth.de/id/eprint/43141 |