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Bio-based polycarbonate from limonene oxide and CO₂ with high molecular weight, excellent thermal resistance, hardness and transparency

Titelangaben

Hauenstein, Oliver ; Reiter, M. ; Agarwal, Seema ; Rieger, B. ; Greiner, Andreas:
Bio-based polycarbonate from limonene oxide and CO₂ with high molecular weight, excellent thermal resistance, hardness and transparency.
In: Green Chemistry. Bd. 18 (2016) Heft 3 . - S. 760-770.
ISSN 1463-9262
DOI: https://doi.org/10.1039/C5GC01694K

Volltext

Link zum Volltext (externe URL): Volltext

Abstract

Completely bio-based, high molecular weight (>100 kDa) poly(limonene carbonate) (PLimC) with attractive thermal (glass transition temperature, Tg = 130°C) and optical properties (transmission 94%, haze 0.75%) was prepared by coupling bio-based limonene oxide (LO) and carbon dioxide (CO₂) using a β-diiminate zinc catalyst (bdi)Zn(OAc). The molar mass of the polymer could be controlled by changing the ratio of catalyst and monomer, keeping molar mass dispersities low. The synthesis of the LO with very high content (>85%) of trans-isomer and absence of impurities with hydroxyl functionality was also established, which was necessary to obtain a high molar mass of polymer and almost quantitative conversion of epoxide during polymerisation. The upscaled syntheses of both the monomer and the polymer (>1 kg per batch) were readily realised, suggesting an easy transfer to pilot plant scale. The polymerisation kinetics were studied suggesting a second order dependence on LO concentration, wherefrom a mechanism is proposed with an alternating insertion of LO and CO₂. The effect of chain-ends on the thermal stability of PLimC was studied with a thermal desorption unit coupled with gas chromatography-mass spectrometry (GC-MS) experiments. PLimC with thermal stability as high as 240°C could be achieved using appropriate end-capping agents. PLimC is characterised by excellent transparency and hardness.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Institutionen der Universität: Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Lehrstuhl Makromolekulare Chemie II
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Lehrstuhl Makromolekulare Chemie II > Lehrstuhl Makromolekulare Chemie II - Univ.-Prof. Dr. Andreas Greiner
Fakultäten
Titel an der UBT entstanden: Ja
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik > 540 Chemie
Eingestellt am: 14 Aug 2018 10:38
Letzte Änderung: 22 Nov 2022 12:28
URI: https://eref.uni-bayreuth.de/id/eprint/45434