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Synthesis of iron(II) complexes with asymmetric N2O2 coordinating Schiff base-like ligands and their spin crossover properties

Title data

Bauer, Wolfgang ; Ossiander, Tanja ; Weber, Birgit:
Synthesis of iron(II) complexes with asymmetric N2O2 coordinating Schiff base-like ligands and their spin crossover properties.
In: Frontiers of Chemical Science and Engineering. Vol. 12 (20 May 2018) Issue 3 . - pp. 400-408.
ISSN 2095-0179
DOI: https://doi.org/10.1007/s11705-018-1753-4

Abstract in another language

The synthesis of new Schiff base-like ligands with asymmetric substituents pattern and their iron complexes with pyridine as axial ligand is described. Two of the ligands and one of the iron(II) complexes were characterized by single crystal X-ray structure analysis. One of the the iron(II) complexes shows spin crossover behaviour while the others remain in the high spin state. The influence of the reduced symmetry of the ligand on the properties of the complexes is discussed.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: iron; Schiff base-like ligands; magnetism; spin crossover; X-ray structures
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV > Chair Anorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 17 Aug 2018 06:06
Last Modified: 22 Oct 2018 06:54
URI: https://eref.uni-bayreuth.de/id/eprint/45505