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Iron(II) Spin Crossover Complexes with 4,4'-Dipyridylethyne-Crystal Structures and Spin Crossover with Hysteresis

Title data

Dankhoff, Katja ; Lochenie, Charles ; Weber, Birgit:
Iron(II) Spin Crossover Complexes with 4,4'-Dipyridylethyne-Crystal Structures and Spin Crossover with Hysteresis.
In: Molecules. Vol. 25 (2020) Issue 3 .
ISSN 1420-3049
DOI: https://doi.org/10.3390/molecules25030581

Abstract in another language

Three new iron(II) 1D coordination polymers with cooperative spin crossover behavior showing thermal hysteresis loops were synthesized using N2O2 Schiff base-like equatorial ligands and 4,4’-dipyridylethyne as a bridging, rigid axial linker. One of those iron(II) 1D coordination polymers showed a 73 K wide hysteresis below room temperature, which, upon solvent loss, decreased to a still remarkable 30 K wide hysteresis. Single crystal X-ray structures of two iron(II) coordination polymers and T-dependent powder XRD patterns are discussed to obtain insight into the structure property relationship of those materials.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV > Chair Inorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 05 Feb 2020 12:26
Last Modified: 05 Feb 2020 12:26
URI: https://eref.uni-bayreuth.de/id/eprint/54282