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High Intrinsic Barriers against Spin‐State Relaxation in Iron(II)‐Complex Solutions

Title data

Stock, Philipp ; Pędziński, Thomasz ; Spintig, Nicole ; Grohmann, Andreas ; Hörner, Gerald:
High Intrinsic Barriers against Spin‐State Relaxation in Iron(II)‐Complex Solutions.
In: Chemistry : a European Journal. Vol. 19 (14 January 2013) Issue 3 . - pp. 839-842.
ISSN 1521-3765
DOI: https://doi.org/10.1002/chem.201203784

Project information

Project financing: Deutsche Forschungsgemeinschaft

Abstract in another language

Slow relaxation : Exergonic high‐spin→low‐spin relaxation after photoexcitation has been found to be exceedingly slow in a class of iron(II) complexes with hexadentate imine ligands. The thermal activation barriers that arise between the quintet‐ and singlet‐spin manifolds are the highest ever recorded for spin crossover of isolated molecules in free solution.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV > Chair Inorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 08 Jul 2020 06:23
Last Modified: 08 Jul 2020 06:23
URI: https://eref.uni-bayreuth.de/id/eprint/55724