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Unexpected activity of novel 9-oxabispidine zinc complexes in lactide polymerization

Title data

Börner, Janna ; Flörke, Ulrich ; Döring, Artjom ; Kuckling, Dirk ; Jones, Matthew D. ; Steiner, Melanie ; Breuning, Matthias ; Herres-Pawlis, Sonja:
Unexpected activity of novel 9-oxabispidine zinc complexes in lactide polymerization.
In: Inorganic Chemistry Communications. Vol. 13 (2010) Issue 3 . - pp. 369-371.
ISSN 1387-7003
DOI: https://doi.org/10.1016/j.inoche.2009.12.024

Abstract in another language

The zinc dichlorido and zinc diacetato complexes of the chiral tricyclic 9-oxabispidine (1R,2S,9S)-11-methyl-13-oxa-7,11-diazatricyclo [7.3.1.02,7] tridecane were prepared and characterized by X-ray crystallography. The latter complex was found to catalyze the solvent-free polymerization of d,l-lactide to give polylactide.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: 9-oxabispidines; Chiral diamine; Polylactide; Ring-opening polymerization; X-ray diffraction
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Professor Organic Chemistry > Professor Organic Chemistry - Univ.-Prof. Dr. Matthias Breuning
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 11 Jan 2022 13:37
Last Modified: 11 Jan 2022 13:37
URI: https://eref.uni-bayreuth.de/id/eprint/68309