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Pradhan, Suman ; Das, Shoubhik:
Recent Advances on the Carboxylations of C(sp³)–H Bonds Using CO₂ as the Carbon Source.
In: Synlett.
Bd. 34
(2023)
Heft 12
.
- S. 1327-1342.
ISSN 1437-2096
DOI: https://doi.org/10.1055/a-2012-5317
Abstract
Carbon dioxide (CO2) is widely known as being a sustainable C1 synthon for the synthesis of various carboxylic acid derivatives, including essential natural and unnatural amino acids. While it is sustainable, the high thermodynamic stability and kinetic inertness of the CO2 molecule is a major drawback to its wider use in organic synthesis. However, the reduction of this inert and highly stable CO2 molecule has been carried out successfully over the past few years using various stoichiometric as well as catalytic approaches. Initially, chemists employed transition-metal/transition-metal-free thermochemical methods for the incorporation of CO2 into organic compounds, however, gradually, the introduction of greener approaches such as visible-light-induced photoredox catalysis and electrocatalysis became revolutionary for the synthesis of carboxylic acids under mild reaction conditions. In this short review, we discuss the recent advances in carboxylation reactions via functionalization of the (sp3)C–H bonds of various organic molecules with CO2 using thermochemical, photochemical and electrochemical methods.
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| Publikationsform: | Artikel in einer Zeitschrift |
|---|---|
| Begutachteter Beitrag: | Ja |
| Keywords: | carbon dioxide; transition-metal; transition-metal-free; thermochemical strategy; visible-light-induced photocatalysis; electrocatalysis; reductive C–H carboxylations; carboxylic acids |
| Institutionen der Universität: | Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie Fakultäten Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Lehrstuhl Organische Chemie I > Lehrstuhl Organische Chemie I - Univ.-Prof. Dr. Das Shoubhik Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Lehrstuhl Organische Chemie I |
| Titel an der UBT entstanden: | Nein |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Eingestellt am: | 18 Jul 2023 08:23 |
| Letzte Änderung: | 29 Nov 2023 08:11 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/86123 |