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Molecules containing rare-earth atoms solely bonded by transition metals

Title data

Butovskii, Mikhail V. ; Döring, Christian ; Bezugly, Viktor ; Wagner, Frank R. ; Grin, Yuri ; Kempe, Rhett:
Molecules containing rare-earth atoms solely bonded by transition metals.
In: Nature Chemistry. Vol. 2 (2010) Issue 9 . - pp. 741-744.
ISSN 1755-4349
DOI: https://doi.org/10.1038/nchem.718

Abstract in another language

Although metal-metal bonding is important in the chemistry of both solid-state intermetallic compounds and molecular species, the study of this bonding is limited by the compounds available and it is rarely possible to identify connections between these two areas. In this study, molecular intermetalloids Ln(ReCp(2))(3) (Ln = Sm, Lu and La) have been synthesized that contain lanthanoid metals bound only to transition metals. Although they are highly reactive species, such lanthanoid-core transition-metal-shell compounds can be stable in solution. They mimic the bonding situation of intermetallic compounds, as revealed by a direct comparison of molecular and solid state lanthanoid-transition metal bonding.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: Cyclopentanes/chemical synthesis/chemistry; Lanthanum/chemistry; Lutetium/chemistry; Magnetic Resonance Spectroscopy; Models, Molecular; Organometallic Compounds/chemical synthesis/chemistry; Quantum Theory; Rhenium/chemistry; Samarium/chemistry
Institutions of the University: Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry II
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry II > Chair Anorganic Chemistry II - Univ.-Prof. Dr. Rhett Kempe
Result of work at the UBT: Yes
DDC Subjects: 500 Science
500 Science > 540 Chemistry
Date Deposited: 23 Mar 2015 06:36
Last Modified: 15 Dec 2017 08:05
URI: https://eref.uni-bayreuth.de/id/eprint/8757