on the publication serverTitle data
Lunkenbein, Thomas ; Schieder, Martin ; Bojer, Carina ; Müller, Axel H. E. ; Breu, Josef:
Packing of Cylindrical Keggin-Type Polyoxometalate Hybrid Micelles as a Function of Aspect Ratio.
In: Zeitschrift für physikalische Chemie.
Vol. 226
(August 2012)
Issue 7-8
.
- pp. 815-826.
ISSN 2196-7156
DOI: https://doi.org/10.1524/zpch.2012.0268
Abstract in another language
The packing of cylindrical Keggin-Type polyoxometalate hybrid micelles and its influence on specific surface area was studied as function of aspect ratio. Core-crosslinked cylindrical poly(butadiene-block-2-vinylpyidine) (PB-b-P2VP) micelles were used as templates for mesostructuring phosphomolybdic acid (H3PMo12O40). Prior to hybrid formation the length of the cylindrical PB-b-P2VP micelles was adjsuted by sonication. Depending on the aspect ratio of the cylinders a remarkable and unexpected evolution of specific surface areas was observed. The changes in the specific surface area could be explained by a series of scanning electron microscopy and transmission electron microscopy images and were related to the packing of the 1D nanoobjects.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Keywords: | Surface Area; Sonication; Self-Assembly; Anisometric Hybrid; Non-Woven |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry I > Chair Anorganic Chemistry I - Univ.-Prof. Dr. Josef Breu Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry I |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 21 Mar 2018 14:14 |
| Last Modified: | 21 Mar 2018 14:14 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/9762 |
