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Synthesis and properties of novel poly(p-xylylene)s with aliphatic substituents

Title data

Ishaque, Michael ; Agarwal, Seema ; Greiner, Andreas:
Synthesis and properties of novel poly(p-xylylene)s with aliphatic substituents.
In: e-Polymers. Vol. 2 (July 2002) Issue 1 . - pp. 442-451.
ISSN 1618-7229
DOI: https://doi.org/10.1515/epoly.2002.2.1.442

Official URL: Volltext

Abstract in another language

Poly(p-xylylene)s (PPX) with aliphatic substituents at the alpha position were synthesized by chemical vapor deposition (CVD) via vapor phase pyrolysis of alpha-chloro-1,4-xylenes, or by base-induced dehydrohalogenation of alpha-chloro-1,4-xylenes (Gilch route). These PPXs are soluble under ambient conditions in organic solvents. The glass transition temperature of the tert-butyl substituted PPX is remarkably high. Good thermal stability under nitrogen was observed for the trifluoromethyl substituted PPX. A functionalized compound suitable for polymer analogous reactions is the norbornenyl substituted PPX.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: CHEMICAL-VAPOR-DEPOSITION; POLYMERIZATION
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 13 Apr 2015 08:33
Last Modified: 13 Apr 2015 08:33
URI: https://eref.uni-bayreuth.de/id/eprint/9821