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Intumescent-like behavior of polystyrene synthetic clay nanocomposites

Title data

Schütz, Michael R. ; Kalo, Hussein ; Lunkenbein, Thomas ; Breu, Josef ; Wilkie, Charles A.:
Intumescent-like behavior of polystyrene synthetic clay nanocomposites.
In: Polymer. Vol. 52 (7 July 2011) Issue 15 . - pp. 3288-3294.
ISSN 0032-3861
DOI: https://doi.org/10.1016/j.polymer.2011.05.030

Abstract in another language

A synthetic Li-fluorohectorite with typical aspect ratios around 1000 shows superior thermal, fire and mechanical properties. A comparison between Li-fluorohectorite and MMT underlines the crucial role of the aspect ratio in particular for flame retardancy. Furthermore, solution blending yields a better dispersion of the filler, as compared to melt compounding, which directly transforms into superior properties. Quite surprisingly, the homogenous clay surface layer built during burning of the PS fluorohectorite nanocomposite has such a high gas barrier that an intumescent-like behavior of the char is detectable.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: Fluorohectorite; Exfoliation; MMT
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry I > Chair Anorganic Chemistry I - Univ.-Prof. Dr. Josef Breu
Research Institutions > Collaborative Research Centers, Research Unit > SFB 840 Von partikulären Nanosystemen zur Mesotechnologie
Research Institutions > Collaborative Research Centers, Research Unit > SFB 840 Von partikulären Nanosystemen zur Mesotechnologie > SFB 840 - TP B 3
Graduate Schools > Elite Network Bavaria
Graduate Schools > Elite Network Bavaria > Struktur, Reaktivität und Eigenschaften Oxidischer Materialien
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry I
Research Institutions
Research Institutions > Collaborative Research Centers, Research Unit
Graduate Schools
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 22 Mar 2018 14:12
Last Modified: 22 Mar 2018 14:12
URI: https://eref.uni-bayreuth.de/id/eprint/9878