at Google ScholarTitle data
Agarwal, Seema ; Karl, Marc ; Anfang, S. ; Dehnicke, Kurt ; Greiner, Andreas:
Synthesis and Characterisation of Homopolymers and Copolymers Based on e-Caprolactone and d -Valerolactone Using Organolanthanides.
In: Abstracts of Papers of the American Chemical Society.
Vol. 216
(1998)
Issue 3
.
- U9.
ISSN 0065-7727
Abstract in another language
The palladium-catalyzed crosscoupling reaction of boronic acids and benzyl bromides can be used successfully for the preparation of benzyls in high yield. This C-C coupling reaction was optimized for the synthesis of polybenzyls by model reactions. Different reaction channels were observed here with meta- and para-bis(bromomethyl)benzenes. The main product with 1,3-bis(chloromethyl)benzene was the corresponding 1,3-dibenzylbenzene, but the main product with 1,4-bis(chloromethyl)benzene was the corresponding biaryl resulting from homocoupling of aromatic boronic acid. 1.3-Linked polybenzyls were synthesized based on the results of the model reactions. M̄n's of 2 380 corresponding to a DP of 26 were found based on GPC. No structural defects were detected within the limits of detection.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 16 Apr 2015 06:20 |
| Last Modified: | 24 Feb 2022 13:30 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/10240 |