Title data
Wrackmeyer, Bernd ; Klimkina, Elena V. ; Ackermann, Tamara ; Milius, Wolfgang:
Ferrocenylaluminum-pyridine adducts, lithium tetra(ferrocenyl)alanate, and the molecular structure of tri(ferrocenyl)aluminum-pyridine.
In: Inorganica Chimica Acta.
Vol. 362
(2009)
Issue 11
.
- pp. 3941-3948.
ISSN 0020-1693
DOI: https://doi.org/10.1016/j.ica.2009.05.019
Abstract in another language
Aluminum compounds with up to four ferrocenyl groups (Fc) linked to aluminum were prepared and characterized in solution by NMR spectroscopy (1H, 13C, 27Al NMR), and in one case, tri(ferrocenyl)aluminum-pyridine Fc3Al-py in the solid state by X-ray structural analysis. The attempts to stabilize the unsymmetrical species R2Al-Fc and RAl(Fc)2 (R = Me, Et) as the pyridine adducts were partially successful, although it proved difficult to suppress the formation of species containing Al–Cl functions completely.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry I Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 20 Mar 2018 09:53 |
| Last Modified: | 14 Sep 2022 09:53 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/10448 |

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