at Google ScholarTitle data
Wrackmeyer, Bernd ; Bihlmayer, Christoph ; Shahid, Khadija ; Milius, Wolfgang:
Reaction of 9-Borabicyclo[3.3.1]nonane with Alkyn-1-yltin Compounds : Molecular Structure of the 9-Propyn-1-yl-9-borabicyclo[3.3.1]nonane Pyridine Adduct.
In: Zeitschrift für Naturforschung B.
Vol. 64
(2009)
Issue 4
.
- pp. 399-402.
ISSN 1865-7117
DOI: https://doi.org/10.1515/znb-2009-0407
Abstract in another language
Trimethyl- and triethyl(propyn-1-yl)tin react with 9-borabicyclo[3.3.1.]nonane (9-BBN) mainly by exchange of the propynyl group against hydrogen, accompanied by numerous side reaction. This is in contrast to the findings for other alkynyltin compounds bearing a second bulky substituent at the C≡C bond. The exchange product, 9-propyn-1-yl-9-borabicyclo[3.3.1]nonane, was isolated as its crystalline pyridine adduct and fully characterised by NMR spectroscopy in solution and X-ray structural analysis in the solid state
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Keywords: | Alkynyltin Compounds; 9-BBN; Exchange; NMR; X-Ray |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry I Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 23 Mar 2018 10:11 |
| Last Modified: | 23 Mar 2018 10:11 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/10450 |