at Google ScholarTitle data
Wrackmeyer, Bernd ; Klimkina, Elena V. ; Milius, Wolfgang:
Synthesis, Characterization and Reactivity of Dinuclear and Trinuclear Aluminum-Bridged Ferrocenophanes.
In: European Journal of Inorganic Chemistry.
Vol. 2009
(July 2009)
Issue 21
.
- pp. 3163-3171.
ISSN 1099-0682
DOI: https://doi.org/10.1002/ejic.200900273
Abstract in another language
Ferrocene derivatives bearing substituents with aluminum in the 1,1′-positions, in the absence of donor ligands, possess rather unusual structural features. Starting from various dipyridine adducts of such 1,1′-disubstituted ferrocene derivatives, it proved possible to trap the pyridine as the adducts R3Al(py) and monitor the formation of dinuclear and trinuclear aluminum-bridged ferrocenophanes in solution by NMR spectroscopy. For the first time, the dynamic behaviour of such complexes was studied and a complete set of NMR spectroscopic data has been reported. The dinuclear complex [Fe(η5-C5H4)2]2Al3Et5 was characterized by X-ray structural analysis.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Keywords: | Metallocenes; Aluminum; NMR spectroscopy; Structure elucidation; Cyclophanes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry I Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 23 Mar 2018 10:25 |
| Last Modified: | 23 Mar 2018 10:25 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/10451 |