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Tetra(alkynyl)silanes, a 3,6-Disila-triyne, a 3,6,9-Trisila-tetrayne, a 1,3,4,6-Tetrasiladiyne, and Bis(trimethylstannyl)ethyne : Molecular Structures and Solid-state NMR Studies

Title data

Wrackmeyer, Bernd ; Khan, Ezzat ; Badshah, Amin ; Molla, Elias ; Thoma, Peter ; Tok, Oleg L. ; Milius, Wolfgang ; Kempe, Rhett ; Senker, Jürgen:
Tetra(alkynyl)silanes, a 3,6-Disila-triyne, a 3,6,9-Trisila-tetrayne, a 1,3,4,6-Tetrasiladiyne, and Bis(trimethylstannyl)ethyne : Molecular Structures and Solid-state NMR Studies.
In: Zeitschrift für Naturforschung B. Vol. 65 (2010) . - pp. 119-127.
ISSN 1865-7117
DOI: https://doi.org/10.1515/znb-2010-0204

Abstract in another language

The molecular structures of three alkynylsilanes, tetrakis(ethynyl-p-tolyl)silane, 3,3,6,6,-tetra-methyl-3,6-disila-triyne, 3,3,6,6,9,9,-hexamethyl-3,6,9-trisila-tetrayne, and of bis(trimethylstannyl)- ethyne have been determined by X-ray diffraction. The same alkynylsilanes, and in addition 1,2-bis(trimethylsilylethynyl)-1,1,2,2-tetramethyldisliane, were studied by solid-state 13 Cand 29 Si MAS NMR spectroscopy. The results of these measurements were compared with crystallographic evidence and also with relevant solution-state NMR data.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry I
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II > Chair Inorganic Chemistry II - Univ.-Prof. Dr. Rhett Kempe
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 26 Mar 2018 07:17
Last Modified: 26 Mar 2018 07:17
URI: https://eref.uni-bayreuth.de/id/eprint/10457