at Google ScholarTitle data
Brandukova-Szmikowski, Natalia E. ; Agarwal, Seema ; Greiner, Andreas:
Synthesis of OH-functionalized poly(p-xylylene)s by reductive coupling polymerization of aromatic dialdehydes with stoichiometric amounts of divalent samarium compounds.
In: Acta Polymerica.
Vol. 50
(1999)
Issue 1
.
- pp. 35-39.
ISSN 1521-4044
DOI: https://doi.org/10.1002/(SICI)1521-4044(19990101)50:1<35::AID-APOL35>3.0.CO;2-H
Abstract in another language
Reductive coupling of aromatic carbonyl compounds in the presence of stoichiometric amounts of Sm(II) compounds such as SmI2, SmI2/TMSiCl, SmBr2, Sm/TMSiBr, SmCp2 resulted in hydrobenzoin derivatives. OH-functionalized poly(p-xylylene)s (OH-PPX) were obtained by reductive coupling of aromatic dialdehydes. The usage of solubilizing groups as well as the use of trimethylsilylchloride (TMSiCl) and trimethylsilylbromide (TMSiBr) enhanced the polymerizability of monomers under study. In spite of moderate yields high molecular weight polymers were obtained.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Additional notes: | ISI:000078195900004 |
| Keywords: | ORGANIC-SYNTHESIS; CARBONYL-COMPOUNDS; LANTHANIDES; REAGENT; IODIDE |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 29 May 2015 09:41 |
| Last Modified: | 24 Feb 2022 13:33 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/14472 |