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The twofold superstructure of titanium(III) oxybromide at T = 17.5 K

Title data

Palatinus, Lukas ; Schönleber, Andreas ; van Smaalen, Sander:
The twofold superstructure of titanium(III) oxybromide at T = 17.5 K.
In: Acta Crystallographica Section C. Vol. 61 (2005) Issue 5 . - i47-i48.
ISSN 1600-5759
DOI: https://doi.org/10.1107/S010827010500867X

Abstract in another language

The low-temperature (T = 17.5 K) structure of titanium(III) oxybromide, TiOBr, is reported as a twofold superstructure of the crystal structure at room temperature. Weak superlattice reflections were measured with synchrotron radiation X-rays and were analyzed by structure refinements employing superspace techniques. Both the low-temperature and the room-temperature structures of TiOBr are isostructural with the corresponding structures of TiOCl. The results indicate that at low temperatures TiOBr is in a spin-Peierls state, similar to that of TiOCl, but with the modulations and relevant interactions smaller than in the latter compound.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences > Chair Crystallography
Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences > Chair Crystallography > Chair Crystallography - Univ.-Prof. Dr. Sander van Smaalen
Faculties
Faculties > Faculty of Mathematics, Physics und Computer Science
Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 530 Physics
Date Deposited: 16 Mar 2016 10:48
Last Modified: 16 Mar 2016 10:48
URI: https://eref.uni-bayreuth.de/id/eprint/31850