Title data
Jordan, Nicola A. ; Battle, Peter D. ; van Smaalen, Sander ; Wunschel, Markus:
Structural Chemistry and Magnetic Properties of Incommensurate Sr₁₊ₓ(CoₓMn₁₋ₓ)O₃.
In: Chemistry of Materials.
Vol. 15
(2003)
Issue 22
.
- pp. 4262-4267.
ISSN 1520-5002
DOI: https://doi.org/10.1021/cm031096
Abstract in another language
The incommensurate, modulated crystal structures of Sr1+x(CoxMn1-x)O3 (x ≈ 0.266 and 0.280) have been refined by a (3+1)D superspace profile analysis of neutron powder diffraction data. The structures are related to the 2H perovskite structure and consist of two subsystems, [CoxMn1-xO3]∞ chains containing face-sharing MnO6 octahedra and CoO6 trigonal prisms (albeit with some cation site inversion), separated from each other by [Sr]∞ chains. The observed structures are closely related to those expected for the idealized compositions Sr14Co3Mn8O33 and Sr9Co2Mn5O21. Both of the compositions investigated show hysteresis in their magnetic behavior below 13 K.
Further data
Item Type: | Article in a journal |
---|---|
Refereed: | Yes |
Institutions of the University: | Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences > Chair Crystallography Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences > Chair Crystallography > Chair Crystallography - Univ.-Prof. Dr. Sander van Smaalen Faculties Faculties > Faculty of Mathematics, Physics und Computer Science Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences |
Result of work at the UBT: | Yes |
DDC Subjects: | 500 Science > 530 Physics |
Date Deposited: | 18 Mar 2016 08:00 |
Last Modified: | 15 Jul 2022 10:42 |
URI: | https://eref.uni-bayreuth.de/id/eprint/31908 |