at Google ScholarTitle data
Beck, Horst P. ; Schramm, Manfred ; Haberkorn, Robert ; Dinnebier, Robert E. ; Stephens, Peter W.:
Synthesis and Crystal Structure of Rb₆Pb₅Cl₁₆.
In: Zeitschrift für anorganische und allgemeine Chemie.
Vol. 624
(1998)
Issue 3
.
- pp. 393-398.
ISSN 1521-3749
DOI: https://doi.org/10.1002/(SICI)1521-3749(199803)624:3<393::AID-ZAAC393>3.0.CO;2-V
Abstract in another language
The synthesis of a hitherto unknown 6 : 5 phase in the quasi-binary system RbCl/PbCl2 and its structure determination is reported. The compound Rb6Pb5Cl16 crystallizes in the tetragonal space group P4/mbm with a large variety of different coordination polyhedra for the cations. Special feature of the structure is a statistical distribution of Rb and Pb at one of the cation sites with a ratio of 1 : 3 as defined by electroneutrality. There is no evidence for symmetry reduction by ordering.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Keywords: | Ternary halide; lone pair cation; high coordination |
| Institutions of the University: | Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences > Chair Crystallography Faculties Faculties > Faculty of Mathematics, Physics und Computer Science Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science > 530 Physics |
| Date Deposited: | 14 Jun 2016 08:53 |
| Last Modified: | 14 Jun 2016 08:53 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/32667 |