Title data
van Smaalen, Sander ; Dinnebier, Robert E. ; Schnelle, W. ; Holleman, Iwan ; von Helden, Gert ; Meijer, Gerard:
Phase transitions of CO-intercalated C 60 crystals.
In: Europhysics Letters.
Vol. 43
(1998)
Issue 3
.
- pp. 302-307.
ISSN 0295-5075
DOI: https://doi.org/10.1209/epl/i1998-00356-y
Abstract in another language
We report the temperature dependence of the specific heat of (CO) x C 60 , and the temperature dependence of the lattice parameter, as determined by X-ray powder diffraction. A first-order phase transition and a glass transition are found to occur at temperatures below the corresponding transition temperatures of pure C 60 . The transition temperatures depend on x . Specific-heat measurements on a sample with x ≈ 0.5 show the orientational ordering transition at T c = 248.8 K and the glass transition at T g = 83.9 K. Contrary to pure C 60 , the temperature dependence of the lattice parameter of (CO) x C 60 ( x ≈ 0.67) does not show an anomaly at the glass transition, which is explained by the already expanded lattice of (CO) x C 60 . The energy difference between major and minor orientations is determined as 19.1 meV.
Further data
Item Type: | Article in a journal |
---|---|
Refereed: | Yes |
Institutions of the University: | Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences > Chair Crystallography Faculties Faculties > Faculty of Mathematics, Physics und Computer Science Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences |
Result of work at the UBT: | Yes |
DDC Subjects: | 500 Science > 530 Physics |
Date Deposited: | 14 Jun 2016 09:51 |
Last Modified: | 14 Jun 2016 09:51 |
URI: | https://eref.uni-bayreuth.de/id/eprint/32672 |