at Google ScholarTitle data
Dinnebier, Robert E. ; Olbrich, Falk ; Bendele, G. M.:
Cyclopentadienylcaesium by High-Resolution X-ray Powder Diffraction.
In: Acta Crystallographica Section C.
Vol. 53
(1997)
Issue 6
.
- pp. 699-701.
ISSN 1600-5759
DOI: https://doi.org/10.1107/S0108270197001984
Abstract in another language
The structure of solid (\it η\sp 5-cyclopentadienyl)caesium, CsC${\sb 5}$H${\sb 5}$, has been refined by high-resolution powder X-ray diffraction. Atomic parameters based on the isostructural Rb analogue were used in the starting model. The compound crystallizes in the space group {\it Pnma} with {\it Z} = 4 and unit-cell parameters {\it a} = 11.3664(2), {\it b} = 8.8648(2) and {\it c} = 5.7200(1){\AA}. Cs(C${\sb 5}$H${\sb 5}$) shows a polymeric zigzag chain, a so-called multidecker structure, with an average Cs{---}Cp${\sb centroid}$ distance of 3.140(5){\AA}. Cs(C${\sb 5}$H${\sb 5}$) contains a single chain along the {\it a} axis. The chains are bent with a Cp${\sb centroid}${---}Cs{---}Cp${\sb centroid}$ angle of 129.7(1){$^\circ$}.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences > Chair Crystallography Faculties Faculties > Faculty of Mathematics, Physics und Computer Science Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science > 530 Physics |
| Date Deposited: | 14 Jun 2016 14:00 |
| Last Modified: | 14 Jun 2016 14:00 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/32681 |