at Google ScholarTitle data
Katzke, Hannelore ; Czank, M. ; Depmeier, Wulf ; van Smaalen, Sander:
On the incommensurately modulated structure of ∊′-LiₓV₂O₅ at room temperature.
In: Philosophical Magazine B.
Vol. 75
(1997)
Issue 5
.
- pp. 757-767.
ISSN 1463-6417
DOI: https://doi.org/10.1080/13642819708202352
Abstract in another language
Abstract Electron diffraction was used to study the lithium-intercalated V2O5 bronzes Li x V2O5. In the course of these investigations a new incommensurately modulated structure was detected at room temperature. The space group of the basic structure is Pmmn; the superspace group characterizing the one-dimensionally modulated structure is found to be Pmmn (0 γ ½). The incommensurate component γ of the modulation vector q is a function of the lithium stoichiometry and varies between γ = 0.531(4) and γ = 0.550(4) for ∊′-Li x V2O5 with 0.605(3) ≤ x ≤ 0.620(3). In the present paper we propose that an important contribution to the modulation results from repulsive Li+-Li+ forces, which impose an incommensurate ordering of the Li+ ions along b∗ in strings of cuboctahedral cavities between adjacent V2O5 layers.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences > Chair Crystallography Faculties Faculties > Faculty of Mathematics, Physics und Computer Science Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science > 530 Physics |
| Date Deposited: | 15 Jun 2016 08:49 |
| Last Modified: | 31 Aug 2021 06:27 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/32682 |