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Room-temperature sol–gel synthesis of organic ligand-capped ZnO nanoparticles

Titelangaben

Zobel, Mirijam ; Chatterjee, Haimantee ; Matveeva, Galina ; Kolb, Ute ; Neder, Reinhard B.:
Room-temperature sol–gel synthesis of organic ligand-capped ZnO nanoparticles.
In: Journal of Nanoparticle Research. Bd. 17 (2015) Heft 5 . - 200.
ISSN 1572-896X
DOI: https://doi.org/10.1007/s11051-015-3006-5

Abstract

Powders of zinc oxide nanoparticles with individual particle sizes below 10 nm in diameter are readily produced in base-induced sol–gel processes from ethanolic solutions of zinc acetate dihydrate. These particles are covered with acetate molecules and without further stabilization, they grow when stored as a powder. Here, we present three organic ligands, which reproducibly stabilize individual particle sizes <5 nm within the agglomerated powders for extended periods of time, up to months. Citric acid and 1,5-diphenyl-1,3,5-pentanetrione result in average diameters of 3 nm, whereas dimethyl-L-tartrate stabilizes 2.1 nm. X-ray diffraction and pair distribution function analysis were used to investigate the structural properties of the particles. TEM data confirm the individual particle size and crystallinity and show that the particles are agglomerated without structural coherence. Besides the introduction of these novel ligands for ZnO nanoparticles, we investigated, in particular, the influence of each synthesis step onto the final nanoparticle size in the powder. Previous studies often reported the employed synthesis parameters, but did not motivate the reasoning for their choice based on detailed experimental observations. Herein, we regard separately the steps of (i) the synthesis of the colloids, (ii) their precipitation, and (iii) the drying of the resulting gel to understand the role of the ligands therein. ZnO particles only covered with acetate grow to 5 nm during the drying process, whereas particles with any of the additional ligands retain their colloidal size of 2–3 nm. This clearly shows the efficient binding and effect of the presented ligands.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Keywords: ZnO; Nanoparticle; Sol–gel synthesis; Organic ligand; Room temperature synthesis
Institutionen der Universität: Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Juniorprofessur Festkörperchemie - Mesostrukturierte Materialien
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Ehemalige ProfessorInnen > Juniorprofessur Festkörperchemie - Mesostrukturierte Materialien - Juniorprof. Dr. Mirijam Zobel
Fakultäten
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Ehemalige ProfessorInnen
Titel an der UBT entstanden: Nein
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik > 500 Naturwissenschaften
500 Naturwissenschaften und Mathematik > 540 Chemie
Eingestellt am: 23 Jan 2017 13:29
Letzte Änderung: 03 Mai 2024 09:17
URI: https://eref.uni-bayreuth.de/id/eprint/35695