at Google ScholarTitle data
Ionov, Leonid ; Minko, Sergiy ; Stamm, Manfred ; Gohy, Jean-François ; Jérôme, Robert ; Scholl, Andreas:
Reversible Chemical Patterning on Stimuli-Responsive Polymer Film : Environment-Responsive Lithography.
In: Journal of the American Chemical Society.
Vol. 125
(2003)
Issue 27
.
- pp. 8302-8306.
ISSN 1520-5126
DOI: https://doi.org/10.1021/ja035560n
Abstract in another language
We report on a novel type of chemical patterning based on thin stimuli−responsive polymer films. The basic concept is the permanent storage (writing) of a pattern, which is reversibly developed and erased upon exposure to appropriate environment, e.g., solvent, pH, and temperature. The smart surface is fabricated from the mixed brush of poly(2-vinylpyridine) and polyisoprene. The mixed brush demonstrates switching behavior upon exposure to different solvents. Cross-linking of polyisoprene via illumination through a photomask results in formation of patterns with suppressed switching. Due to the contrast in switching between illuminated and dark areas, exposure of the smart surface to different solvents causes either reversible formation or erasing of chemical contrast between the illuminated and dark areas. Thus, the pattern surface can very locally attract colloidal particles or can be wetted by water only upon exposure to the special solvent which introduces the contrast between the illuminated and dark areas. Appearance of the patterns indicates particular environment and can be used for local switching of adsorption.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Engineering Science > Professor Biofabrication > Professor Biofabrication - Univ.-Prof. Dr. Leonid Ionov Faculties Faculties > Faculty of Engineering Science Faculties > Faculty of Engineering Science > Professor Biofabrication |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 21 Jun 2017 11:48 |
| Last Modified: | 09 Mar 2022 14:02 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/37714 |