at Google ScholarTitle data
Schneider, Andreas ; Gade, Lutz H. ; Breuning, Matthias ; Bringmann, Gerhard ; Scowen, Ian J. ; McPartlin, Mary:
Cooperative Reactivity of Unsupported Early-Late Heterobimetallics : Ring Opening and Subsequent Decarbonylation of Biaryllactones.
In: Organometallics.
Vol. 17
(1998)
Issue 9
.
- pp. 1643-1645.
ISSN 1520-6041
DOI: https://doi.org/10.1021/om980007d
Abstract in another language
Reaction of the heterodinuclear complex [HC{SiMe2N(2-FC6H3)}3Zr−FeCp(CO)2] (1) with 1,3-dimethyl-6H-benzo[b]naphtho[1,2-d]pyranone (2) and 1,3-dimethoxy-6H-benzo[b]-naphtho-[1,2-d]pyranone (3) led to immediate ring opening of the lactones to yield products which combine the biaryl fragment with aryloxyzirconium and acyl−FeCp(CO)2 units. The latter slowly decarbonylate to yield the corresponding heterobimetallic complexes in which the {MCp(CO)2} fragment is directly bonded to the naphthalene ring.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Professor Organic Chemistry > Professor Organic Chemistry - Univ.-Prof. Dr. Matthias Breuning Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Professor Organic Chemistry |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 03 Jul 2017 11:36 |
| Last Modified: | 12 Jan 2022 14:01 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/38231 |