at Google ScholarTitle data
Dankhoff, Katja ; Lochenie, Charles ; Puchtler, Florian ; Weber, Birgit:
Solvent Influence on the Magnetic Properties of Iron(II) Spin-Crossover Coordination Compounds with 4,4'-Dipyridylethyne as Linker.
In: European Journal of Inorganic Chemistry.
Vol. 2016
(2016)
Issue 13-14
.
- pp. 2136-2143.
ISSN 1099-0682
DOI: https://doi.org/10.1002/ejic.201501175
Abstract in another language
New iron(II) coordination polymers with solvent-dependent spin-crossover behaviour have been synthesised by using an N2O2 Schiff base like ligand and 4,4′-dipyridylethyne as the bridging axial ligand in different solvents. The effects of different solvents and preparation methods (temperature, concentration) on the magnetic properties have been investigated. Annealing the coordination polymers prepared by the same method but in different solvents led to the same compound exhibiting the same three-step spin crossover independent of the magnetic properties of the solvated species. The X-ray structures of the axial ligand, an iron(II) dimer and one of the iron(II) coordination polymers are discussed. Powder X-ray diffraction analysis was additionally used for further comparison of the compounds.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV > Chair Inorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 25 Jul 2017 11:29 |
| Last Modified: | 07 Oct 2022 05:31 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/38801 |