Title data
Lochenie, Charles ; Gebauer, Andreas ; Klimm, Ottokar ; Puchtler, Florian ; Weber, Birgit:
Iron(II) spin crossover complexes with diaminonaphthalene-based Schiff base-like ligands : 1D coordination polymers.
In: New Journal of Chemistry.
Vol. 40
(2016)
Issue 5
.
- pp. 4687-4695.
ISSN 1369-9261
DOI: https://doi.org/10.1039/C5NJ02470F
Abstract in another language
The synthesis of iron(II) coordination polymers of new Schiff base-like ligands with an extended π-system is described. In total sixteen new compounds were synthesised. The complexes were characterised by X-ray powder diffraction and magnetic measurements. Four of these complexes remain in the low-spin state and six remain in the high-spin state in the entire temperature range investigated. The remaining six complexes show a spin crossover behaviour with a cooperative spin transition (28 and 40 K wide hysteresis loops) in two cases. The influence of the extended aromatic system on cooperative interactions is discussed.
Further data
Item Type: | Article in a journal |
---|---|
Refereed: | Yes |
Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV > Chair Inorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV |
Result of work at the UBT: | Yes |
DDC Subjects: | 500 Science > 540 Chemistry |
Date Deposited: | 25 Jul 2017 11:45 |
Last Modified: | 07 Oct 2022 05:32 |
URI: | https://eref.uni-bayreuth.de/id/eprint/38803 |