at Google ScholarTitle data
Lochenie, Charles ; Heinz, Julia ; Milius, Wolfgang ; Weber, Birgit:
Iron(II) spin crossover complexes with diaminonaphthalene-based Schiff base-like ligands : mononuclear complexes.
In: Dalton Transactions.
Vol. 44
(2015)
Issue 41
.
- pp. 18065-18077.
ISSN 1477-9234
DOI: https://doi.org/10.1039/C5DT03048J
Abstract in another language
The synthesis of new Schiff base-like ligands with extended π-system and their iron complexes is described. Some of the iron(II) complexes with N-heterocycles as axial ligands show spin crossover behaviour. The influence of the extended aromatic system on cooperative interactions is investigated by single crystal X-ray structure analysis, X-ray powder diffraction, and magnetic measurements. A combination of C–H⋯π and C–H⋯O interactions is made responsible for up to 10 K wide thermal hysteresis loops.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV > Chair Inorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 25 Jul 2017 12:11 |
| Last Modified: | 25 Jul 2017 12:11 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/38805 |