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1D iron(II) spin crossover coordination polymers with 3,3'-azopyridine : kinetic trapping effects and spin transition above room temperature

Title data

Schönfeld, Sophie ; Lochenie, Charles ; Thoma, Peter ; Weber, Birgit:
1D iron(II) spin crossover coordination polymers with 3,3'-azopyridine : kinetic trapping effects and spin transition above room temperature.
In: CrystEngComm. Vol. 17 (2015) Issue 29 . - pp. 5389-5395.
ISSN 1466-8033
DOI: https://doi.org/10.1039/C5CE00800J

Abstract in another language

Two new iron(II) 1D coordination polymers with spin crossover behaviour were synthesised using 3,3′-azopyridine as bridging axial ligand and N2O2 coordinating Schiff base-like equatorial ligands. The X-ray structures of both complexes were solved revealing very different packing patterns for the two complexes. Magnetic measurements reveal a spin transition with hysteresis and kinetic trapping effects at lower temperatures for one complex and a spin transition above room temperature for the second complex.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV > Chair Inorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 25 Jul 2017 12:39
Last Modified: 25 Jul 2017 12:39
URI: https://eref.uni-bayreuth.de/id/eprint/38807