at Google ScholarTitle data
Schlamp, Stephan ; Thoma, Peter ; Bauer, Tobias ; Kempe, Rhett ; Weber, Birgit:
A New Iron(II) Complex with Strongly Saddle Shaped Schiff Base like Ligand.
In: Zeitschrift für anorganische und allgemeine Chemie.
Vol. 639
(2013)
Issue 10
.
- pp. 1763-1767.
ISSN 1521-3749
DOI: https://doi.org/10.1002/zaac.201300176
Abstract in another language
The synthesis of two new Schiff base like ligands containing a 1, 8-diaminonaphthalene unit in order to improve π–π interactions between the molecules is described. The corresponding iron(II), copper(II), and nickel(II) complexes were synthesized and characterized using NMR spectroscopy, magnetic measurements, and for the iron(II) complex X-ray structure analysis. The crystal structure shows a strongly saddle shaped ligand. In contrast to related complexes with a phenylene unit that prefer an octahedral coordination sphere, this complex crystallizes pentacoordinate. The keto-group of a neighboring complex serves as axial ligand resulting in the formation of infinite chains. Magnetic susceptibility measurements reveal nearly ideal curie behavior for the copper(II) and the iron(II) complex.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV > Chair Inorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 26 Jul 2017 10:58 |
| Last Modified: | 26 Jul 2017 10:58 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/38819 |