Iron(II) spin transition coordination polymers with a zigzag structure

Title data

Bauer, Wolfgang ; Dîrtu, Marinela M. ; Garcia, Yann ; Weber, Birgit:
Iron(II) spin transition coordination polymers with a zigzag structure.
In: CrystEngComm. Vol. 14 (2012) Issue 4 . - pp. 1223-1231.
ISSN 1466-8033
DOI: https://doi.org/10.1039/C2CE06253D

Official URL:

Abstract in another language

The synthesis and characterisation of seven iron(II) 1D chain coordination polymers with tetradentate Schiff-base like equatorial ligands and bis(4-pyridylmethyl)sulfide (bpms) as a flexible bridging axial ligand is reported. This new family of materials displays a wide spectrum of spin transition properties in the solid state ranging from gradual, abrupt, incomplete to even step-wise that have all been characterized by SQUID magnetometry. The X-ray structure analysis of two complexes at several temperatures is discussed in the frame of their spin crossover properties.

Further data

Item Type:	Article in a journal
Refereed:	Yes
Institutions of the University:	Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV > Chair Inorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV
Result of work at the UBT:	Yes
DDC Subjects:	500 Science > 540 Chemistry
Date Deposited:	26 Jul 2017 11:57
Last Modified:	04 Sep 2020 10:11
URI:	https://eref.uni-bayreuth.de/id/eprint/38823