Title data
Schlamp, Stephan ; Schulten, Johanna ; Betz, Richard ; Bauch, Tobias ; Mudring, Anja Verena ; Weber, Birgit:
Synthesis of Anionic Spin Crossover Complexes with Schiff Base like Ligands.
In: Zeitschrift für anorganische und allgemeine Chemie.
Vol. 638
(2012)
Issue 7-8
.
- pp. 1093-1102.
ISSN 0044-2313
DOI: https://doi.org/10.1002/zaac.201200162
Abstract in another language
The reaction of neutral iron(II) complexes of tetradentate Schiff base like ligands with the pseudohalogenides SCN–, OCN–, and CN– as monodentate axial ligands was investigated. In solution the formation of octahedral complexes could be confirmed and it was possible to follow a spin transition by T-dependent 1H NMR spectroscopy. In the solid only pentacoordinate complexes were obtained and the X-ray structure of five monoanionic pentacoordinate iron(II) complexes and an interesting trinuclear complex are discussed.
Further data
Item Type: | Article in a journal |
---|---|
Refereed: | Yes |
Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV > Chair Inorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV |
Result of work at the UBT: | Yes |
DDC Subjects: | 500 Science > 540 Chemistry |
Date Deposited: | 26 Jul 2017 12:06 |
Last Modified: | 26 Jul 2017 12:06 |
URI: | https://eref.uni-bayreuth.de/id/eprint/38826 |