at Google ScholarTitle data
Pfaffeneder, Toni ; Bauer, Wolfgang ; Weber, Birgit:
X-ray Structure and Magnetic Properties of Two New Iron(II) 1D Coordination Polymers with Bis(imidazolyle)methane as Bridging Ligand.
In: Zeitschrift für anorganische und allgemeine Chemie.
Vol. 636
(2010)
Issue 1
.
- pp. 183-187.
ISSN 1521-3749
DOI: https://doi.org/10.1002/zaac.200900291
Abstract in another language
The reaction of iron(II) acetate with the tetradentate Schiff base like ligands H2L1 ((E,E)-[{diethyl 2,2′-[1,2-phenylenebis(iminomethylidyne)]bis[3-oxobutanato]) and H2L2 ([3,3′]-[1,2-phenylene-bis(iminomethylidyne)]bis(2,4-pentane-dionato)-N,N′,O2,O2′]) leads to the formation of the octahedral N2O4 coordinated iron complexes [FeL1(MeOH)2] and [FeL2(MeOH)2], respectively. Conversion of both with bimm (bis(1-imidazolyle)methane) leads to the 1D coordination polymers [FeL1(bimm)]·0.5MeOH (1) and [FeL2(bimm)] (2). Compound 1 is a pure high-spin (HS) complex, which was characterised by using magnetic measurements and X-ray structure analysis. Compound 2 undergoes an irregular and incomplete thermal spin transition.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV > Chair Inorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 27 Jul 2017 12:20 |
| Last Modified: | 27 Jul 2017 12:20 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/38839 |