at Google ScholarTitle data
Weber, Birgit ; Obel, Jaroslava:
Synthesis and Characterisation of a New Schiff-Base-like Ligand and its Iron(II) Complexes.
In: Zeitschrift für anorganische und allgemeine Chemie.
Vol. 635
(2009)
Issue 15
.
- pp. 2474-2479.
ISSN 1521-3749
DOI: https://doi.org/10.1002/zaac.200900241
Abstract in another language
The reaction of iron(II) acetate with the tetradentate Schiff base like ligand H2L [(E,E)-[{diethyl 2,2’-[4,5-dihydroxy-1,2-phenylenebis(iminomethylidyne)]bis3-oxobutanato}]) leads to the formation of the octahedral N2O4 coordinated complex [FeL(MeOH)2]·MeOH (1). Conversion of 1 with N-methylimidazole (N-meim) leads to the N4O2 coordinated complex [FeL(N-meim)2]·MeOH (2). Both complexes are pure HS compounds that were characterised using magnetic measurements and X-ray crystallography. A special attention was given to the role of the two hydroxyl groups at the phenyl ring on the formation of a hydrogen bond network and the influence of this network on the magnetic properties.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV > Chair Inorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 27 Jul 2017 12:52 |
| Last Modified: | 27 Jul 2017 12:52 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/38847 |