Low-Temperature Sol-Gel Synthesis of Nanostructured Polymer/Titania Hybrid Films based on Custom-Made Poly(3-Alkoxy Thiophene)

Title data

Niedermeier, Martin A. ; Rawolle, Monika ; Lellig, Philipp ; Körstgens, Volker ; Herzig, Eva M. ; Buffet, Adeline ; Roth, Stephan V. ; Gutmann, Jochen S. ; Fröschl, Thomas ; Hüsing, Nicola ; Müller-Buschbaum, Peter:
Low-Temperature Sol-Gel Synthesis of Nanostructured Polymer/Titania Hybrid Films based on Custom-Made Poly(3-Alkoxy Thiophene).
In: ChemPhysChem. Vol. 14 (2013) Issue 3 . - pp. 597-602.
ISSN 1439-4235
DOI: https://doi.org/10.1002/cphc.201200808

Official URL:

Abstract in another language

A low-temperature route to directly obtain polymer/titania hybrid films is presented. For this, a custom-made poly(3-alkoxy thiophene) was synthesized and used in a sol-gel process together with an ethylene-glycol-modified titanate (EGMT) as a suitable titania precursor. The poly(3-alkoxy thiophene) was designed to act as the structure-directing agent for titanium dioxide through selective incorporation of the titania precursor. The nanostructured titania network, embedded in the polymer matrix, is examined with atomic force microscopy (AFM) and scanning electron microscopy (SEM) measurements. By means of the scattering technique grazing incidence wide-angle X-ray scattering (GIWAXS), a high degree of crystallinity of the polymer as well as successful transformation of the precursor into the rutile phase of titania is verified. UV/Vis measurements reveal an absorption behavior around 500 nm which is similar to poly(3-hexyl thiophene), a commonly used polymer for photoelectronic applications, and in addition, the typical UV absorption behavior of rutile titania is observed.

Further data

Item Type:	Article in a journal
Refereed:	Yes
Keywords:	hybrid films; low temperature; polythiophene; sol-gel processes; titania
Institutions of the University:	Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics > Juniorprofessor Experimental Physics VII - Dynamics and Structure Formation > Juniorprofessor Experimental Physics VII - Dynamics and Structure Formation - Juniorprof. Dr. Eva M. Herzig Faculties Faculties > Faculty of Mathematics, Physics und Computer Science Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics > Juniorprofessor Experimental Physics VII - Dynamics and Structure Formation
Result of work at the UBT:	No
DDC Subjects:	500 Science > 530 Physics
Date Deposited:	06 Oct 2017 09:17
Last Modified:	20 Oct 2022 10:55
URI:	https://eref.uni-bayreuth.de/id/eprint/39915