at Google ScholarTitle data
Noor, Awal ; Qayyum, Sadaf ; Bauer, Tobias ; Schwarz, Stefan ; Weber, Birgit ; Kempe, Rhett:
CO₂ and SO₂ activation by a Cr–Cr quintuple bond.
In: Chemical Communications.
Vol. 50
(2014)
Issue 86
.
- pp. 13127-13130.
ISSN 1364-548X
DOI: https://doi.org/10.1039/C4CC05071A
Abstract in another language
A quintuply bonded dichromium complex stabilized by aminopyridinato ligands activates CO2 and SO2 by reducing the (formal) bond order of the metal-metal bonds. Oxygen abstraction is observed during CO2 activation. SO2 activation proceeds via formation of a unique dithionite complex/coordination. Furthermore, N2O activation was investigated and the formation of a tetrameric Cr-oxo complex was observed.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II > Chair Inorganic Chemistry II - Univ.-Prof. Dr. Rhett Kempe Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science 500 Science > 500 Natural sciences 500 Science > 540 Chemistry |
| Date Deposited: | 18 Dec 2017 10:47 |
| Last Modified: | 31 Jan 2022 12:42 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/41023 |