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Kunz, Daniel A. ; Leitl, Markus J. ; Schade, Lukas ; Schmid, Jasmin ; Bojer, Beate ; Schwarz, Ulrich T. ; Ozin, Geoffrey A. ; Yersin, Hartmut ; Breu, Josef:
Quasi-epitaxial Growth of [Ru(bpy)₃]²⁺ by Confinement in Clay Nanoplatelets Yields Polarized Emission.
In: Small.
Bd. 11
(2014)
Heft 7
.
- S. 792-796.
ISSN 1613-6829
DOI: https://doi.org/10.1002/smll.201400826
Abstract
A nano confinement strategy is presented to control the spatial orientation and emission polarization of phosphorescent metal complexes. Through nano-confinement of the phosphorescent metal complex [Ru(bpy)3 ](2+) by attaching it to anionic clay nanoplatelets, it is possible to simultaneously lock the spatial orientation of the complex and fix its emission polarization. This quasi-epitaxial approach may provide a future work strategy directed at light emitting diodes and lasers.