at Google ScholarTitle data
Zhang, Guoying ; Irrgang, Torsten ; Dietel, Thomas ; Kallmeier, Fabian ; Kempe, Rhett:
Manganese‐catalyzed Dehydrogenative Alkylation or α‐Olefination of Alkyl‐N‐Heteroaromatics by Alcohols.
In: Angewandte Chemie International Edition.
Vol. 57
(2018)
Issue 29
.
- pp. 9131-9135.
ISSN 1521-3773
DOI: https://doi.org/10.1002/anie.201801573
Abstract in another language
Catalysis involving earth‐abundant transition metals is an option to help save our rare noble metal resources and is especially interesting if novel reactivity or selectivity patterns are observed. We report here on a novel reaction: the dehydrogenative alkylation or α‐olefination of alkyl‐N‐heteroaromatics by alcohols. Manganese complexes developed in our laboratory catalyze the reaction efficiently. Fe and Co complexes stabilized by such ligands are essentially inactive. Hydrogen is liberated during the reaction and bromo or iodo functional groups and olefins can be tolerated. A variety of alkyl‐N‐heteroaromatics can be functionalized, and benzyl and aliphatic alcohols undergo the reaction.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Additional notes: | Early view |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II > Chair Inorganic Chemistry II - Univ.-Prof. Dr. Rhett Kempe Faculties |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science 500 Science > 540 Chemistry |
| Date Deposited: | 04 May 2018 06:26 |
| Last Modified: | 12 Sep 2018 05:07 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/43994 |