at Google ScholarTitle data
Forberg, Daniel ; Schwob, Tobias ; Kempe, Rhett:
Catalytic condensation for the formation of polycyclic heteroaromatic compounds.
In: Nature Communications.
Vol. 9
(2018)
.
- 1751.
ISSN 2041-1723
DOI: https://doi.org/10.1038/s41467-018-04143-6
Abstract in another language
The conservation of our global element resources is a challenge of the utmost urgency. Since aliphatic and aromatic alcohols are accessible from abundant indigestible kinds of biomass, first and foremost lignocellulose, the development of novel chemical reactions converting alcohols into important classes of compounds is a particularly attractive carbon conservation and CO2-emission reduction strategy. Herein, we report the catalytic condensation of phenols and aminophenols or aminoalcohols. The overall reaction of this synthesis concept proceeds via three steps: hydrogenation, dehydrogenative condensation and dehydrogenation. Reusable catalysts recently developed in our laboratory mediate these reactions highly efficient. The scope of the concept is exemplarily demonstrated by the synthesis of carbazoles, quinolines and acridines, the structural motifs of which figure prominently in many important natural products, drugs and materials.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry II > Chair Inorganic Chemistry II - Univ.-Prof. Dr. Rhett Kempe Faculties |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science 500 Science > 540 Chemistry |
| Date Deposited: | 04 May 2018 06:29 |
| Last Modified: | 10 Aug 2023 11:08 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/43996 |