at Google ScholarTitle data
Wang, Hui ; Bethke, Christian ; Hermann, Markus ; Frenking, Gernot ; Agarwal, Seema:
Structural Exploration of Phantom Oligoguanidine from Asymmetric Diamine and Guanidine Hydrochloride.
In: Macromolecular Chemistry and Physics.
Vol. 217
(2016)
Issue 16
.
- pp. 1834-1841.
ISSN 1521-3935
DOI: https://doi.org/10.1002/macp.201600154
Abstract in another language
Condensation reaction of asymmetric triamine (spermidine) with guanidine hydrochloride provides a phantom structure with selective formation of rings in the repeat unit. The intermolecular condensation between amine and guanidine hydrochloride can provide either a linear structure or six‐ or seven‐membered rings in the repeat unit by elimination of one or three molecules of ammonia, respectively, per repeat unit. The preference of formation of rings and mechanistic aspects are studied by matrix‐assisted laser desorption/ionization time‐of‐flight mass spectrometry, 1D, 2D NMR, and quantum chemical calculations.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 13 Aug 2018 07:45 |
| Last Modified: | 08 Oct 2020 08:59 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/45418 |