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Reversible gold nanorod alignment in mechano-responsive elastomers

Title data

Pletsch, Holger ; Tebbe, Moritz ; Dulle, Martin ; Förster, Beate ; Fery, Andreas ; Förster, Stephan ; Greiner, Andreas ; Agarwal, Seema:
Reversible gold nanorod alignment in mechano-responsive elastomers.
In: Polymer. Vol. 66 (2015) . - pp. 167-172.
ISSN 0032-3861
DOI: https://doi.org/10.1016/j.polymer.2015.04.037

Abstract in another language

Inspired by an increasing demand for stimuli-controlled assembly of nanostructures, mechano-responsive nanocomposites are designed with tremendous scope in material applications. Providing switchable properties by means of mechanical stimulation, elastomer-incorporated gold nanorods (AuNR) are presented herein. Stepless and reversible control over the orientational AuNR alignment – and therefore over macroscopic anisotropy – is exerted by uniaxial film elongation. In context of optical applications, substantial impact on the plasmonic properties within adjustable spectral ranges is demonstrated. Mechano-responsive nanocomposites with high thermal colloidal stability are prepared via a facile hetero-phase ligand exchange procedure where complete coverage of the AuNR surface with hydrophobic ligands is achieved.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner
Faculties
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 16 Aug 2018 07:35
Last Modified: 01 Feb 2022 12:27
URI: https://eref.uni-bayreuth.de/id/eprint/45497