at Google ScholarTitle data
Barth, Klaus ; Richter, Wolfgang:
Small Molecules in Hole-Burning Systems : A Local Antenna for Infrared-Induced Spectral Diffusion Processes.
In: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals.
Vol. 283
(1996)
Issue 1
.
- pp. 225-230.
ISSN 1563-5287
DOI: https://doi.org/10.1080/10587259608037891
Abstract in another language
Light-induced spectral diffusion in photochemical hole-burning systems is investigated with respect to its dependence on the frequency of the irradiated infrared light in the wavelength range between 2 μm and 11 μm. The investigated system is polymethylmethacrylate (PMMA) containing up to one volume percent water molecules and doped with free-base phthalocyanine (H2Pc). Different resonant contributions to the infrared-induced spectral diffusion show that the microscopic origin of the observed diffusion process is a reorientation of H2O molecules. A simple kinetic model, based on the idea of two possible sites for each H2O molecule, allows to describe the dependence of the hole-broadening on infrared intensity and illumination time in a very good quantitative fashion.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Keywords: | spectral diffusion; hole-burning |
| Institutions of the University: | Faculties > Faculty of Mathematics, Physics und Computer Science Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics > Chair Experimental Physics IX - Spectroscopy of Soft Matter > Chair Experimental Physics IX - Spectroscopy of Soft Matter - Univ.-Prof. Dr. Jürgen Köhler Faculties Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics > Chair Experimental Physics IX - Spectroscopy of Soft Matter |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science 500 Science > 530 Physics |
| Date Deposited: | 13 Dec 2013 08:32 |
| Last Modified: | 10 Dec 2024 12:58 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/46 |