Iron(II) and Iron(III) Complexes of Tridentate NNO Schiff Base‐like Ligands – X‐ray Structures and Magnetic Properties : dedicated to Professor Wolfgang Bensch on occasion of his 65th birthday

Title data

Dankhoff, Katja ; Schneider, Sandra ; Nowak, René ; Weber, Birgit:
Iron(II) and Iron(III) Complexes of Tridentate NNO Schiff Base‐like Ligands – X‐ray Structures and Magnetic Properties : dedicated to Professor Wolfgang Bensch on occasion of his 65th birthday.
In: Zeitschrift für anorganische und allgemeine Chemie. Vol. 644 (2018) Issue 24 . - pp. 1839-1848.
ISSN 1521-3749
DOI: https://doi.org/10.1002/zaac.201800359

Official URL:

Abstract in another language

A series of new [Fe(L)2] iron(II) and [Fe(L)2]X iron(III) complexes is presented with varying tridentate NNO coordinating Schiff base‐like ligands (L–) and different counterions (X– = Cl–, Br–, I– BF4–, PF6–, and ClO4–) in the case of the iron(III) complexes. The crystal structures of one iron(II) and three iron(III) complexes are discussed, as well as the magnetic properties of the complexes regarding the possibility of the observation of spin crossover. While the three iron(II) complexes are predominantly high spin, in the case of the iron(III) complexes spin crossover was observed for the majority of the complexes (10 out of 12). Additionally, the optical properties and electrochemical behavior in solution was investigated and the results are compared with related systems from literature.

Further data

Item Type:	Article in a journal
Refereed:	Yes
Additional notes:	Early View Version before inclusion in an issue
Institutions of the University:	Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV > Chair Inorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV
Result of work at the UBT:	Yes
DDC Subjects:	500 Science > 540 Chemistry
Date Deposited:	18 Oct 2018 08:50
Last Modified:	06 Apr 2023 08:02
URI:	https://eref.uni-bayreuth.de/id/eprint/46081