at Google ScholarTitle data
Schönfeld, Sophie ; Lochenie, Charles ; Hörner, Gerald ; Weber, Birgit:
Iron(II) complexes with N₂O₂ coordinating Schiff base-like equatorial ligand and 1,2-bis(pyridin-2-ylethynyl)benzene as axial pincer ligand.
In: Journal of Physics: Condensed Matter.
Vol. 31
(2019)
Issue 50
.
- No. 504002.
ISSN 1361-648X
DOI: https://doi.org/10.1088/1361-648X/ab3e92
Abstract in another language
Three new unique mononuclear iron(II) pincer complexes were synthesized using 1,2-bis(pyridin-2-ylethynyl)benzene as axially coordinating pincer ligand and N2O2 coordinating Schiff base-like equatorial ligands. Magnetic susceptibility measurements reveal that all three complexes remain in the high spin state throughout the entire temperature range investigated. Reasons for this are restraining sterical interactions revealed in the single crystal x-ray structure analysis and extended DFT-computational studies of one of the pincer complexes. Those interactions also lead to the formation of unexpected side products during the synthesis such as a complex with two ethanol molecules as axial ligand, whose x-ray structure was determined.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV > Chair Inorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 10 Oct 2019 07:54 |
| Last Modified: | 12 Jul 2022 12:26 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/52731 |