Title data
Dankhoff, Katja ; Lochenie, Charles ; Weber, Birgit:
Iron(II) Spin Crossover Complexes with 4,4'-Dipyridylethyne-Crystal Structures and Spin Crossover with Hysteresis.
In: Molecules.
Vol. 25
(2020)
Issue 3
.
- 581.
ISSN 1420-3049
DOI: https://doi.org/10.3390/molecules25030581
Abstract in another language
Three new iron(II) 1D coordination polymers with cooperative spin crossover behavior showing thermal hysteresis loops were synthesized using N2O2 Schiff base-like equatorial ligands and 4,4’-dipyridylethyne as a bridging, rigid axial linker. One of those iron(II) 1D coordination polymers showed a 73 K wide hysteresis below room temperature, which, upon solvent loss, decreased to a still remarkable 30 K wide hysteresis. Single crystal X-ray structures of two iron(II) coordination polymers and T-dependent powder XRD patterns are discussed to obtain insight into the structure property relationship of those materials.
Further data
Item Type: | Article in a journal |
---|---|
Refereed: | Yes |
Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV > Chair Inorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry IV |
Result of work at the UBT: | Yes |
DDC Subjects: | 500 Science > 540 Chemistry |
Date Deposited: | 05 Feb 2020 12:26 |
Last Modified: | 26 Jan 2023 10:21 |
URI: | https://eref.uni-bayreuth.de/id/eprint/54282 |