Structural Diversity in Layered Hybrid Perovskites, A₂PbBr₄ or AA′PbBr₄, Templated by Small Disc-Shaped Amines

Title data

Guo, Yuan-Yuan ; Yang, Lin-Jie ; Biberger, Simon ; McNulty, Jason A. ; Li, Teng ; Schötz, Konstantin ; Panzer, Fabian ; Lightfoot, Philip:
Structural Diversity in Layered Hybrid Perovskites, A₂PbBr₄ or AA′PbBr₄, Templated by Small Disc-Shaped Amines.
In: Inorganic Chemistry. Vol. 59 (2020) Issue 17 . - pp. 12858-12866.
ISSN 1520-510X
DOI: https://doi.org/10.1021/acs.inorgchem.0c01807

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Abstract in another language

We present three new hybrid layered lead(II) bromide perovskites of generic composition A2PbBr4 or AA′PbBr4 that exhibit three distinct structure types. [TzH]2PbBr4 ([TzH+] = 1,2,4-triazolium) adopts a (001)-oriented layer structure and [AaH]2PbBr4, ([AaH+] = acetamidinium) adopts a (110)-oriented type, whereas [ImH][TzH]PbBr4, ([ImH+] = imidazolium) adopts a rare (110)-oriented structure with enhanced corrugation (i.e., 3 × 3 type). The crystal structures of each are discussed in terms of the differing nature of the templating molecular species. Photoluminescent spectra for each are reported and the behaviors discussed in relation to the different structure of each composition.

Further data

Item Type:	Article in a journal
Refereed:	Yes
Additional notes:	PMID: 32805998
Institutions of the University:	Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics > Chair Experimental Physics II - Optoelectronics of Soft Matter Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics > Chair Experimental Physics II - Optoelectronics of Soft Matter > Chair Experimental Physics II - Optoelectronics of Soft Matter - Univ.-Prof. Dr. Anna Köhler Faculties Faculties > Faculty of Mathematics, Physics und Computer Science
Result of work at the UBT:	Yes
DDC Subjects:	500 Science > 530 Physics
Date Deposited:	03 Sep 2020 06:51
Last Modified:	06 Feb 2023 13:04
URI:	https://eref.uni-bayreuth.de/id/eprint/56755