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Terrestrial solar radiation driven photodecomposition of ciprofloxacin in clinical wastewater applying mesostructured iron(III) oxide

Title data

Wagner, Daniel R. ; Ament, Kevin ; Mayr, Lina ; Martin, Thomas ; Blößer, André ; Schmalz, Holger ; Marschall, Roland ; Wagner, Friedrich E. ; Breu, Josef:
Terrestrial solar radiation driven photodecomposition of ciprofloxacin in clinical wastewater applying mesostructured iron(III) oxide.
In: Environmental Science and Pollution Research. Vol. 28 (2020) . - pp. 6222-6231.
ISSN 1614-7499
DOI: https://doi.org/10.1007/s11356-020-10899-6

Official URL: Volltext

Project information

Project title:
Project's official title
Project's id
SFB 840 - Von partikulären Nanosystemen zur Mesotechnologie
No information

Project financing: Deutsche Forschungsgemeinschaft

Abstract in another language

Cationic cylindrical polymer brushes based on polybutadiene-block-poly(2-vinylpyridine) were applied as structure-directing agent for mesostructuring Fe2O3 nanoparticles into nanotubes. After temperature-controlled template removal, the obtained non-woven catalysts were tested for the photodegradation of ciprofloxacin under terrestrial solar radiation. At a slightly basic pH value, as typically encountered in clinical wastewaters, the mesostructured Fe2O3 shows a 4.5 times faster degradation of ciprofloxacin than commercial Aeroxide® TiO2 P25. Even wide-bandgap ZnO, mesostructured in the same way, is 1.6 times slower. Moreover, the non-woven-like structure of the catalyst allows for easy recovery of the catalyst and operation in a continuous flow reactor.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: Wastewater treatment; Photocatalysis; Ciprofloxacin; Fe2O3; Mesostructured; Cylindrical polymer brushes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry I
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Inorganic Chemistry I > Chair Inorganic Chemistry I - Univ.-Prof. Dr. Josef Breu
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Physical Chemistry III
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Physical Chemistry III > Chair Physical Chemistry III - Univ.-Prof. Dr. Roland Marschall
Research Institutions > Affiliated Institutes > Bavarian Polymer Institute (BPI)
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Research Institutions
Research Institutions > Affiliated Institutes
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 17 Nov 2020 07:48
Last Modified: 25 Mar 2021 11:24
URI: https://eref.uni-bayreuth.de/id/eprint/59868